AuCl-catalyzed synthesis of benzyl-protected substituted phenols: A formal [3+3] approach

被引：34

作者：

Huang, Xiaogen ^{[1
]}

Zhang, Liming ^{[1
]}

机构：

[1] Univ Nevada, Dept Chem, Reno, NV 89557 USA

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 22期

关键词：

D O I：

10.1021/ol7021356

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A AuCl-catalyzed synthesis of highly substituted, benzyl-protected phenols is developed. This reaction unites enal/enones and benzyl allenyl ether in a [3+3] fashion in two steps, allowing flexibility in phenol synthesis and excellent control of substitution at the benzene ring.

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页码：4627 / 4630

页数：4

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