Energy transfer, proton transfer and electron transfer reactions within zeolites

被引:128
作者
Ramamurthy, V [1 ]
Lakshminarasimhan, P
Grey, CP
Johnston, LJ
机构
[1] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA
[2] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA
[3] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada
关键词
D O I
10.1039/a803871f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The chemistry of olefins in zeolites illustrates both the potential complexity and utility of zeolites as reaction media. Of particular interest are the changes in product selectivity that result from carrying out oxidation reactions in the constrained space of the zeolite cavity. Since zeolites are capable of promoting proton and electron transfer reactions one needs to be particularly careful in the choice of a zeolite as a reaction medium.
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页码:2411 / 2424
页数:14
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