Modern diffusion-ordered NMR spectroscopy in chemistry of supramolecular systems: the scope and limitations

被引:38
作者
Kharlamov, S. V. [1 ]
Latypov, Sh K. [1 ]
机构
[1] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia
基金
俄罗斯基础研究基金会;
关键词
NUCLEAR-MAGNETIC-RESONANCE; GRADIENT SPIN-ECHO; HIGH-RESOLUTION DIFFUSION; STUDYING TRANSLATIONAL DIFFUSION; EDDY-CURRENT COMPENSATION; CHEMICAL-MIXTURE ANALYSIS; MOLECULAR-MASS ESTIMATION; RANK ANNIHILATION METHOD; PULSED-FIELD GRADIENTS; AMIDE PROTON-EXCHANGE;
D O I
10.1070/RC2010v079n08ABEH004148
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The concept of diffusion-ordered NMR spectroscopy (self-diffusion coefficients measurement in high-resolution mode) is considered. The most important aspects of interpretation of experimental data, as well as the scope and limitations of the available theoretical and phenomenological models relating the self-diffusion coefficient to the size or mass of the molecular system are discussed.
引用
收藏
页码:635 / 653
页数:19
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