Modern diffusion-ordered NMR spectroscopy in chemistry of supramolecular systems: the scope and limitations

被引：38

作者：

Kharlamov, S. V. ^{[1
]}

Latypov, Sh K. ^{[1
]}

机构：

[1] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia

来源：

RUSSIAN CHEMICAL REVIEWS | 2010年 / 79卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

NUCLEAR-MAGNETIC-RESONANCE; GRADIENT SPIN-ECHO; HIGH-RESOLUTION DIFFUSION; STUDYING TRANSLATIONAL DIFFUSION; EDDY-CURRENT COMPENSATION; CHEMICAL-MIXTURE ANALYSIS; MOLECULAR-MASS ESTIMATION; RANK ANNIHILATION METHOD; PULSED-FIELD GRADIENTS; AMIDE PROTON-EXCHANGE;

D O I：

10.1070/RC2010v079n08ABEH004148

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The concept of diffusion-ordered NMR spectroscopy (self-diffusion coefficients measurement in high-resolution mode) is considered. The most important aspects of interpretation of experimental data, as well as the scope and limitations of the available theoretical and phenomenological models relating the self-diffusion coefficient to the size or mass of the molecular system are discussed.

引用

页码：635 / 653

页数：19

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