Gas-phase observation of multiply charged C60 anions

被引：16

作者：

Cammarata, V ^{[1
]}

Guo, T ^{[1
]}

Illies, A ^{[1
]}

Li, LD ^{[1
]}

Shevlin, P ^{[1
]}

机构：

[1] Auburn Univ, Dept Chem & Biochem, Auburn, AL 36849 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2005年 / 109卷 / 12期

关键词：

D O I：

10.1021/jp044785x

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Gas-phase observation Of C-60(1-), C-60(3-), and C-60(4-) anions generated at platinum and gold electrodes and detected by electrochemical/electro spray mass spectrometry is reported. The anions were electrochemically generated from solutions Of C-60 dissolved in toluene/acetonitrile as well as from reduction Of C-60 films on gold electrode surfaces. The gas-phase observation Of C-60(3-) and C-60(4-), despite the fact that they have negative electron affinities, is a result of a Coulombic barrier to electron loss. The fact that C-60(2-) was not detected in these experiments is ascribed to its limited solubility under the reaction conditions. These studies, which demonstrate the gas-phase kinetic stability Of C-60(4-) and C-60(3-) illustrate the promise of electrochernical/electro spray mass spectrometry for the study of metastable anions.

引用

页码：2765 / 2767

页数：3

共 43 条

[1] Novel C60-based building blocks derived from C602- anion [J].

Allard, E ;

Delaunay, J ;

Cheng, FY ;

Cousseau, J ;

Ordúna, J ;

Garín, J .

ORGANIC LETTERS, 2001, 3 (22) :3503-3506

[2] Chemical generation and reactivity of C602-.: High-yield and regioselective alkylation of [60, Ih] fullerene [J].

Allard, E ;

Rivière, L ;

Delaunay, J ;

Dubois, D ;

Cousseau, J .

TETRAHEDRON LETTERS, 1999, 40 (40) :7223-7226

[3] 2 DIFFERENT FULLERENES HAVE THE SAME CYCLIC VOLTAMMETRY [J].

ALLEMAND, PM ;

KOCH, A ;

WUDL, F ;

RUBIN, Y ;

DIEDERICH, F ;

ALVAREZ, MM ;

ANZ, SJ ;

WHETTEN, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (03) :1050-1051

[4] Electronic properties of charged fullerenes characterized by EPR and Vis-NIR spectroscopy [J].

Baumgarten, M ;

Gherghel, L .

APPLIED MAGNETIC RESONANCE, 1996, 11 (02) :171-182

[5] EPR AND OPTICAL-ABSORPTION SPECTRA OF REDUCED BUCKMINSTERFULLERENE [J].

BAUMGARTEN, M ;

GUGEL, A ;

GHERGHEL, L .

ADVANCED MATERIALS, 1993, 5 (06) :458-461

[6] CONSIDERED NOVEL AROMATIC SYSTEMS .11. DIAMAGNETIC POLYANIONS OF THE C60 AND C70 FULLERENES - PREPARATION, C-13 AND LI-7 NMR SPECTROSCOPIC OBSERVATION, AND ALKYLATION WITH METHYL-IODIDE TO POLYMETHYLATED FULLERENES [J].

BAUSCH, JW ;

PRAKASH, GKS ;

OLAH, GA ;

TSE, DS ;

LORENTS, DC ;

BAE, YK ;

MALHOTRA, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (08) :3205-3206

[7] SYNTHESIS AND ELECTRONIC CHARACTERIZATION OF DISCRETE BUCKMINSTERFULLERIDE SALTS - C-60(2-) AND C-60(3-) [J].

BHYRAPPA, P ;

PAUL, P ;

STINCHCOMBE, J ;

BOYD, PDW ;

REED, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (23) :11004-11005

[8] THE C-60(2-) FULLERIDE ION [J].

BOYD, PDW ;

BHYRAPPA, P ;

PAUL, P ;

STINCHCOMBE, J ;

BOLSKAR, RD ;

SUN, YP ;

REED, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (10) :2907-2914

[9] RAPID AND EFFICIENT SYNTHESIS OF ALKALI-METAL C-60 COMPOUNDS IN LIQUID-AMMONIA [J].

BUFFINGER, DR ;

ZIEBARTH, RP ;

STENGER, VA ;

RECCHIA, C ;

PENNINGTON, CH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (20) :9267-9270

[10] Novel water-soluble hexa(sulfobutyl)fullerenes as potent free radical scavengers [J].

Chi, Y ;

Bhonsle, JB ;

Canteenwala, T ;

Huang, JP ;

Shiea, J ;

Chen, BJ ;

Chiang, LY .

CHEMISTRY LETTERS, 1998, (05) :465-466

← 1 2 3 4 5 →