Recent advances in transition-metal catalyzed reactions using molecular oxygen as the oxidant

被引：1104

作者：

Shi, Zhuangzhi ^{[1
]}

Zhang, Chun ^{[1
]}

Tang, Conghui ^{[1
]}

Jiao, Ning ^{[1
,2
]}

机构：

[1] Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China

[2] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2012年 / 41卷 / 08期

基金：

美国国家科学基金会;

关键词：

C-H BONDS; AEROBIC OXIDATIVE AMINATION; PRIMARY AROMATIC-AMINES; CROSS-COUPLING REACTION; SYMMETRICAL 1,4-DISUBSTITUTED 1,3-DIYNES; ALPHA-DIAZOCARBONYL COMPOUNDS; WACKER-TYPE OXIDATION; CARBON TRIPLE BOND; HECK-TYPE REACTION; TERMINAL ALKYNES;

D O I：

10.1039/c2cs15224j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For green and sustainable chemistry, molecular oxygen is considered as an ideal oxidant due to its natural, inexpensive, and environmentally friendly characteristics, and therefore offers attractive academic and industrial prospects. This critical review introduces the recent advances over the past 5 years in transition-metal catalyzed reactions using molecular oxygen as the oxidant. This review highlights the scope and limitations, as well as the mechanisms of these oxidation reactions (184 references).

引用

页码：3381 / 3430

页数：50

共 330 条

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