New reactivity patterns of copper(I) and other transition metal NHC complexes:: application to ATRC and related reactions

被引:38
作者
Bull, James A. [1 ]
Hutchings, Michael G. [1 ]
Lujan, Cristina [1 ]
Quayle, Peter [1 ]
机构
[1] Univ Manchester, Sch Chem, DyStar Uk Ltd, Manchester M13 9PL, Lancs, England
关键词
ATRC; Kharasch; cyclisation; radical; copper; carbene; NHC; nickel; ruthenium; palladium; Grubbs;
D O I
10.1016/j.tetlet.2007.12.084
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Pre-formed transition metal-NHC complex is shown to be an effective catalyst for Atom Transfer Radical Cyclisation (ATRC) reactions. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1352 / 1356
页数:5
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