The hydrophobic effect drives the recognition of hydrocarbons by an anionic metal-ligand cluster

被引：81

作者：

Biros, Shannon M. ^{[1
]}

Bergman, Robert G. ^{[1
]}

Raymond, Kenneth N. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 40期

关键词：

D O I：

10.1021/ja075236i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the complexation of a series of n(-) and cycloalkanes by an anionic, metal-ligand cluster carrying a 12(-) charge. This host also encapsulates cyclodecane isomers such as adamantane, the dicyclopentadienes, and the decalins. The relative binding affinities of these guests for the [Ga4L6](12-) cluster are reported and attributed to the hydrophobic effect.

引用

页码：12094 / +

页数：3

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