One pot synthesis of 3,5-alkylated acetophenone and methyl benzoate derivatives via an anionic domino process

被引:33
作者
Ballini, R [1 ]
Barboni, L [1 ]
Fiorini, D [1 ]
Giarlo, G [1 ]
Palmieri, A [1 ]
机构
[1] Univ Camerino, Dipartimento Sci Chim, I-62032 Camerino, Italy
关键词
D O I
10.1039/b500846h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of primary 1,3-dinitroalkanes with 2-ene-1,4-dione or 2-ene-4-oxo ester derivatives in acetonitrile with DBU as base, allow the one pot synthesis of 3,5-alkylated acetophenones and methyl benzoate derivatives respectively via an anionic domino process.
引用
收藏
页码:2633 / 2634
页数:2
相关论文
共 36 条
[1]   Stereoselective Michael addition reactions of 5-glyco-4-nitrocyclohex-1-enes [J].
Areces, P ;
Gil, MV ;
Higes, FJ ;
Román, E ;
Serrano, JA .
TETRAHEDRON LETTERS, 1998, 39 (46) :8557-8560
[2]   One-pot synthesis of 1,3-dinitroalkanes under heterogeneous catalysis [J].
Ballini, R ;
Bosica, G ;
Fiorini, D ;
Palmieri, A .
SYNTHESIS-STUTTGART, 2004, (12) :1938-1940
[3]   Conjugate addition of nitroalkanes to N-substituted maleimides.: Synthesis of 3-alkylsuccinimides and pyrrolidines [J].
Ballini, R ;
Bosica, G ;
Cioci, G ;
Fiorini, D ;
Petrini, M .
TETRAHEDRON, 2003, 59 (20) :3603-3608
[4]   One-pot synthesis of polyfunctionalized α,β-unsaturated nitriles from nitroalkanes [J].
Ballini, R ;
Fiorini, D ;
Gil, MV ;
Palmieri, A .
TETRAHEDRON LETTERS, 2003, 44 (50) :9033-9034
[5]   δ-Nitroalkanols as precursors for the one-pot synthesis of substituted tetrahydrofurans [J].
Ballini, R ;
Fiorini, D ;
Gil, MV ;
Palmieri, A ;
Román, E ;
Serrano, JA .
TETRAHEDRON LETTERS, 2003, 44 (14) :2795-2797
[6]  
Ballini R, 2002, SYNTHESIS-STUTTGART, P681
[7]   MICHAEL ADDITION OF NITROALKANES TO DIMETHYL MALEATE WITH DBU - A NEW DIRECT METHOD FOR THE SYNTHESIS OF POLYFUNCTIONALIZED ALPHA,BETA-UNSATURATED ESTERS [J].
BALLINI, R ;
RINALDI, A .
TETRAHEDRON LETTERS, 1994, 35 (49) :9247-9250
[8]  
Ballini R, 2001, SYNTHESIS-STUTTGART, P2003
[9]   Stereoselective synthesis of (E)-4-alkylidenecyclopent-2-en-1-ones by a tandem ring closure-Michael addition-elimination [J].
Ballini, R ;
Bosica, G ;
Fiorini, D ;
Gil, MV ;
Petrini, M .
ORGANIC LETTERS, 2001, 3 (09) :1265-1267
[10]   A DIRECT METHOD FOR THE SYNTHESIS OF POLYFUNCTIONALIZED UNSATURATED CARBONYL DERIVATIVES BY MICHAEL ADDITION OF NITROALKANES TO ENEDIONES WITH THE HELP OF DBU [J].
BALLINI, R ;
BOSICA, G .
TETRAHEDRON, 1995, 51 (14) :4213-4222