Poly(Lactic Acid)/Layered Silicate Nanocomposite Films: Morphology, Mechanical Properties, and Effects of γ-Radiation

被引：9

作者：

Dadbin, Susan ^{[1
]}

Naimian, Faranak ^{[1
]}

Akhavan, Azam ^{[1
]}

机构：

[1] Nucl Sci & Technol Res Inst, Radiat Applicat Res Sch, Tehran, Iran

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2011年 / 122卷 / 01期

关键词：

biodegradable; biomaterial; poly(lactic acid); nanocomposite; gamma-irradiation; ACID); POLY(L-LACTIDE);

D O I：

10.1002/app.33985

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 [高分子化学与物理];

摘要：

Poly(Lactic acid) (PLA)-layered silicate nanocomposite films were prepared by solvent casting method. The films were irradiated with Co-60 radiation facility at dose of 30 kGy. The effect of gamma irradiation on mechanical properties of the neat PLA and nanocomposites was evaluated by data obtained from tensile testing measurements. The tensile strength of the irradiated PLA films increased with addition of 1 wt % triallyl cyanurate indicating crosslink formation. Significant ductile behavior was observed in the PLA nanocomposites containing 4 pph of nanoclay. Incorporation of nanoclay particles in the PLA matrix stimulated crystal growth as it was studied by differential scanning calorimetry. The morphology of the nanocomposites characterized by transmission electron microscopy and X-ray diffraction revealed an exfoliated morphology in the PLA nanocomposite films containing 4 pph of nanoclay. Only very small changes were observed in the chemical structure of the irradiated samples as it was investigated by Fourier transform infrared spectroscopy. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 122: 142-149, 2011

引用

页码：142 / 149

页数：8

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