Homoleptic bismuth and antimony complexes of the tripodal [Te(NtBu)3]2- anion

被引：20

作者：

Chivers, T ^{[1
]}

Parvez, M

Schatte, G

Yap, GPA

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

[2] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 07期

关键词：

D O I：

10.1021/ic9814322

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first homoleptic complexes of a tripodal [E((NBu)-Bu-t)(3)](2-) anion (E = S, Se, Te) are prepared by the reaction of {Li-2[Te((NBu)-Bu-t)(3)]}(2) with MCl3 (E = Bi, Sb) in THF or toluene. In the complexes Li{M[Te((NBu)-Bu-t)(3)](2)} the pnicogen is chelated (N, N') to two [Te((NBu)-Bu-t)(3)](2-) anions and the pendant (NBu)-Bu-t groups of these anions are bridged by a Li+ cation.

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页码：1380 / +

页数：3

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