A TE2N6LI4 CAGE CONTAINING THE TRIS(TERT-BUTYLIMIDO)TELLURITE DIANION

被引：58

作者：

CHIVERS, T

GAO, XL

PARVEZ, M

机构：

[1] Department of Chemistry, University of Calgary, Calgary, Alberta

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 22期

关键词：

HETEROCYCLES; LITHIUM COMPOUNDS; NITROGEN COMPOUNDS; TELLURIUM COMPOUNDS;

D O I：

10.1002/anie.199525491

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nonexplosive, easy‐to‐handle TeN reagent is the Li2 derivative of the tris(tert‐butylimido)tellurite dianion 1, which can be prepared from [(tBuN)Te]2(μ‐NtBu)2 and tBuNHLi. The Te2N6Li4 cage in 1 adopts a distorted hexagonal prismatic structure. The reaction of 1 with PhPCl2 or PhBCl2 produces the spirocycle 2 and the four‐membered ring 3, respectively. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

收藏

页码：2549 / 2551

页数：3

相关论文

共 30 条

[1]

Bjcrgvinsson M., 1991, ANGEW CHEM, V103, P1671

[2] SYNTHESIS AND STRUCTURE OF THE 1ST TELLURIUM(III) RADICAL CATION [J].

BJORGVINSSON, M ;

HEINZE, T ;

ROESKY, HW ;

PAUER, F ;

STALKE, D ;

SHELDRICK, GM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (12) :1677-1678

[3]

BJORGVINSSON M, 1992, POLYHEDRON, V10, P2353

[4] TELLURIUM-NITROGEN DOUBLE-BONDS AND A NOVEL TE3N3 RING - FORMATION AND STRUCTURES OF [((T)BUNH)((T)BUN)(3)TE-2]CL, [(T)BUNTEN(T)BU](2), AND [(T)BUNTE](3) [J].

CHIVERS, T ;

GAO, XL ;

PARVEZ, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (08) :2359-2360

[5] IMIDO ANALOGS OF THE TUNGSTATE(VI) AND PERRHENATE(VII) IONS - X-RAY CRYSTAL-STRUCTURES OF LI2W(NBU-TERT)4 AND LI(TMED)RE(NBU-TERT)4 [J].

DANOPOULOS, AA ;

WILKINSON, G ;

HUSSAIN, B ;

HURSTHOUSE, MB .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (14) :896-897

[6]

Edwards A. J., 1994, ANGEW CHEM, V106, P1334

[7] A NEW METHOD FOR THE SYNTHESIS OF HETEROMETALLIC COMPLEXES - SYNTHESES AND STRUCTURES OF [(PHCH(2)CH(2)NLI)(3)SB(THF)](2) AND [SB-3(CYN)(4)(NME(2))(2)]LI [J].

EDWARDS, AJ ;

PAVER, MA ;

RAITHBY, PR ;

RENNIE, MA ;

RUSSELL, CA ;

WRIGHT, DS .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (12) :1277-1279

[8] IMINOAMINOSULFINATES - SYNTHESIS, CRYSTAL-STRUCTURES, AND REARRANGEMENT MONITORED BY LI-7 SOLID-STATE NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY [J].

FREITAG, S ;

KOLODZIEJSKI, W ;

PAUER, F ;

STALKE, D .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (23) :3479-3488

[9]

GREGORY K, 1991, ADV INORG CHEM, V37, P58

[10] NEW PATHWAYS IN TELLURIUM-CHALKOGEN-NITROGEN CHEMISTRY - PREPARATIONS, STRUCTURES, AND PROPERTIES OF TELLURAHETEROCYCLES [J].

HAAS, A ;

PRYKA, M .

CHEMISCHE BERICHTE, 1995, 128 (01) :11-22