Structural direction by the dominant metal

被引：34

作者：

Beswick, MA ^{[1
]}

Mosquera, MEG ^{[1
]}

Wright, DS ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 15期

关键词：

D O I：

10.1039/a800687c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Assessment of the structures of a number of heterometallic alkali metal/p block metal complexes suggests that the p block metals have a dominant role in dictating the structures of these species, since generally greater covalency of the metal-ligand interactions leads to more geometrically rigid metal co-ordination.

引用

页码：2437 / 2443

页数：7

共 35 条

[1] Syntheses and structures of [Sn{NR}(2){Sn(mu-NMe2)}(2)]: Model intermediates in the formation of imido group 14 cages and rings [R = 2,6-pr(2)(i)C(6)H(3) (Dipp), 2,4,6-Me3C6H2 (Mes)] [J].

Allan, RE ;

Beswick, MA ;

Coggan, GR ;

Raithby, PR ;

Wheatley, AEH ;

Wright, DS .

INORGANIC CHEMISTRY, 1997, 36 (23) :5202-5205

[2] Build-up of an Al4P6Li4 cage from an Al4N4 cubane: Synthesis and structure of [Li(OC4H8)](4)[{(AlMe)[mu-P(C6H11)]}(2){mu-P(C6H11)}](2)center dot C(6)H(5)Me [J].

Allan, RE ;

Beswick, MA ;

Raithby, PR ;

Steiner, A ;

Wright, DS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (22) :4153-4154

[3] Synthesis and structure of the heterobimetallic ladder complex [{(MesNH)Sn(μ-Nma)}2(Li.2THF)2] (Mes=2,4,6-Me3C6H2, ma=2-MeOC6H4) [J].

Allan, RE ;

Beswick, MA ;

Feeder, N ;

Kranz, M ;

Mosquera, MEG ;

Raithby, PR ;

Wheatley, AEH ;

Wright, DS .

INORGANIC CHEMISTRY, 1998, 37 (10) :2602-2604

[4] Fragmentation of an imido tin(II) cubane; Syntheses and structures of heterobimetallic complexes containing tin(II) imido and phosphinidine anions [J].

Allan, RE ;

Beswick, MA ;

Cromhout, NL ;

Paver, MA ;

Raithby, PR ;

Steiner, A ;

Trevithick, M ;

Wright, DS .

CHEMICAL COMMUNICATIONS, 1996, (13) :1501-1502

[5]

ALLAN RE, 1994, J CHEM SOC DA, P1995

[6] SYNTHESIS AND STRUCTURE OF [SB2LI2(N(C6H11))4]2 - A CAGE COMPLEX CONTAINING A CORE OF 2 INTERLOCKED BROKEN CUBES [J].

ALTON, RA ;

BARR, D ;

EDWARDS, AJ ;

PAVER, MA ;

RAITHBY, PR ;

RENNIE, MA ;

RUSSELL, CA ;

WRIGHT, DS .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (12) :1481-1482

[7]

ANDO F, 1991, J NUCL CHEM, V15, P2011

[8] LADDER STRUCTURES IN LITHIUM AMIDE CHEMISTRY - SYNTHESES AND SOLID-STATE AND SOLUTION STRUCTURES OF DONOR-DEFICIENT LITHIUM PYRROLIDIDE COMPLEXES, ([H2C(CH2)3NLI]3.PMDETA)2 AND ([H2C(CH2)3NLI]2.TMEDA)2, AND ABINITIO MO CALCULATIONS PROBING RING VS LADDER VS STACK STRUCTURAL PREFERENCES [J].

ARMSTRONG, DR ;

BARR, D ;

CLEGG, W ;

HODGSON, SM ;

MULVEY, RE ;

REED, D ;

SNAITH, R ;

WRIGHT, DS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (13) :4719-4727

[9] Novel octameric structure of the lithium primary amide [{Bu(t)N(H)Li}(8)] and its implication for the directed synthesis of heterometallic imide cages [J].

Barnett, NDR ;

Clegg, W ;

Horsburgh, L ;

Lindsay, DM ;

Liu, QY ;

Mackenzie, FM ;

Mulvey, RE ;

Williard, PG .

CHEMICAL COMMUNICATIONS, 1996, (20) :2321-2322

[10]

BARR D, 1994, ANGEW CHEM INT EDIT, V33, P1875, DOI 10.1002/anie.199418751

← 1 2 3 4 →