Metal-catalysed cleavage of carbon-carbon bonds

被引：435

作者：

Murakami, Masahiro ^{[1
]}

Matsuda, Takanori ^{[2
]}

机构：

[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Kyoto 6158510, Japan

[2] Tokyo Univ Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 04期

关键词：

C-C; INTRAMOLECULAR ARYLCYANATION; ARYLBORONIC ACIDS; RING-EXPANSION; ACTIVATION; ALKYNES; CONSTRUCTION; ARYLATION; INSERTION; CARBOCYANATION;

D O I：

10.1039/c0cc02566f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions cleaving carbon-carbon bonds with the assistance of transition metals as the catalyst have provided various molecular transformations that are otherwise difficult to execute, opening a scenic avenue along organic synthesis. Construction of structural motifs like medium-sized carbocycles and chiral quaternary carbon centres have been set within an access of such paradoxical approaches in the past decade.

引用

页码：1100 / 1105

页数：6

共 47 条

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