Process intensification of encapsulation of functionalized CaCO3 nanoparticles using ultrasound assisted emulsion polymerization

被引：69

作者：

Bhanvase, B. A. ^{[2
]}

Pinjari, D. V. ^{[1
]}

Gogate, P. R. ^{[1
]}

Sonawane, S. H. ^{[2
,3
]}

Pandit, A. B. ^{[1
]}

机构：

[1] Inst Chem Technol, Bombay 400019, Maharashtra, India

[2] Vishwakarma Inst Technol, Pune 411037, Maharashtra, India

[3] N Maharashtra Univ, Dept Chem Technol, Jalgaon 425001, India

来源：

CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION | 2011年 / 50卷 / 11-12期

关键词：

PMMA/CaCO3; nanocomposite; Ultrasound; Emulsion polymerization; Semibatch process; Encapsulation; IN-SITU POLYMERIZATION; MECHANICAL-PROPERTIES; CALCIUM-CARBONATE; NANOCOMPOSITES; PARTICLES; CRYSTALLIZATION; SURFACE; GAS;

D O I：

10.1016/j.cep.2011.09.002

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The present work deals with the use of intensified processes based on the ultrasonic irradiations for the improvement of the process of encapsulation of inorganic nanoparticles into polymer during nanocomposite synthesis process. The cavitational effects produced due to the use of ultrasonic irradiations have been shown to enhance the dispersion of functional nano-inorganic particles into the monomer during polymerization process. The model system is based on the nanocomposite of poly(methyl methacrylate)/calcium carbonate (PMMA/CaCO3) which has been synthesized by ultrasound assisted semibatch emulsion polymerization. CaCO3 nanoparticles were pretreated with myristic acid in order to improve the compatibility of the monomer with the inorganic particles. TEM image of PMMA/CaCO3 composite particles with well-defined core-shell structure give direct evidence of encapsulation. Effect of encapsulation of CaCO3 particles on thermal properties has been evaluated using thermo-gravimetric methods and it has been observed that the nanocomposites have better thermal stability as compared to the PMMA. (C) 2011 Elsevier BY. All rights reserved.

引用

页码：1160 / 1168

页数：9

共 41 条

[31] Design aspects of sonochemical reactors: Techniques for understanding cavitational activity distribution and effect of operating parameters [J].

Sutkar, Vinayak S. ;

Gogate, Parag R. .

CHEMICAL ENGINEERING JOURNAL, 2009, 155 (1-2) :26-36

[32] Silica nanoparticles as surfactants and fillers for latexes made by miniemulsion polymerization [J].

Tiarks, F ;

Landfester, K ;

Antonietti, M .

LANGMUIR, 2001, 17 (19) :5775-5780

[33] Hybrid latex particles coated with silica [J].

Tissot, I ;

Novat, C ;

Lefebvre, F ;

Bourgeat-Lami, E .

MACROMOLECULES, 2001, 34 (17) :5737-5739

[34]

Wang CY, 2007, MAT SCI ENG C-BIO S, V27, P42, DOI 10.1016/j.msec.2006.01.003

[35] Synthesis of hydrophobic CaCO3 nanoparticles [J].

Wang, CY ;

Sheng, Y ;

Zhao, X ;

Pan, Y ;

Hari-Bala ;

Wang, ZC .

MATERIALS LETTERS, 2006, 60 (06) :854-857

[36] Preparation of polymer/inorganic nanoparticles composites through ultrasonic irradiation [J].

Wang, Q ;

Xia, HS ;

Zhang, CH .

JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 80 (09) :1478-1488

[37] Study on in situ preparation of nano calcium carbonate/PMMA composite particles [J].

Wu, Wei ;

He, Taobo ;

Chen, Jian-feng ;

Zhang, Xueqin ;

Chen, Yuxi .

MATERIALS LETTERS, 2006, 60 (19) :2410-2415

[38] Rheological and mechanical properties of PVC/CaCO3 nanocomposites prepared by in situ polymerization [J].

Xie, XL ;

Liu, QX ;

Li, RKY ;

Zhou, XP ;

Zhang, QX ;

Yu, ZZ ;

Mai, YW .

POLYMER, 2004, 45 (19) :6665-6673

[39] EFFECT OF DIPHOSPHONATES ON THE PRECIPITATION OF CALCIUM-CARBONATE IN AQUEOUS-SOLUTIONS [J].

XYLA, AG ;

KOUTSOUKOS, PG .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1987, 83 :1477-1484

[40]

Yang Y, 1999, POLYM ADVAN TECHNOL, V10, P54

← 1 2 3 4 5 →