Direct experimental evidence of a growing length scale accompanying the glass transition

被引:691
作者
Berthier, L [1 ]
Biroli, G
Bouchaud, JP
Cipelletti, L
El Masri, D
L'Hôte, D
Ladieu, F
Pierno, M
机构
[1] Univ Montpellier 2, Lab Colloides Verres & Nanomat, UMR 5587, F-34095 Montpellier, France
[2] CNRS, F-34095 Montpellier, France
[3] CEA Saclay, Serv Phys Theor Orme Merisiers, F-91191 Gif Sur Yvette, France
[4] Capital Fund Management, Sci & Finance, F-75009 Paris, France
关键词
D O I
10.1126/science.1120714
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Understanding glass formation is a challenge, because the existence of a true glass state, distinct from liquid and solid, remains elusive: Glasses are liquids that have become too viscous to flow. An old idea, as yet unproven experimentally, is that the dynamics becomes sluggish as the glass transition approaches, because increasingly larger regions of the material have to move simultaneously to allow flow. We introduce new multipoint dynamical susceptibilities to estimate quantitatively the size of these regions and provide direct experimental evidence that the glass formation of molecular liquids and colloidal suspensions is accompanied by growing dynamic correlation length scales.
引用
收藏
页码:1797 / 1800
页数:4
相关论文
共 32 条
  • [21] Comparative study of the NMR length scale of dynamic heterogeneities of three different glass formers
    Reinsberg, SA
    Heuer, A
    Doliwa, B
    Zimmermann, H
    Spiess, HW
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2002, 307 : 208 - 214
  • [22] Length scale of dynamic heterogeneity in supercooled glycerol near Tg
    Reinsberg, SA
    Qiu, XH
    Wilhelm, M
    Spiess, HW
    Ediger, MD
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2001, 114 (17) : 7299 - 7302
  • [23] Direct observation of molecular cooperativity near the glass transition
    Russell, EV
    Israeloff, NE
    [J]. NATURE, 2000, 408 (6813) : 695 - 698
  • [24] Thermodynamic-kinetic correlations in supercooled liquids: A critical survey of experimental data and predictions of the random first-order transition theory of glasses
    Stevenson, JD
    Wolynes, PG
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (31) : 15093 - 15097
  • [25] Disentangling density and temperature effects in the viscous slowing down of glassforming liquids
    Tarjus, G
    Kivelson, D
    Mossa, S
    Alba-Simionesco, C
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2004, 120 (13) : 6135 - 6141
  • [26] Dynamical susceptibility of glass formers: Contrasting the predictions of theoretical scenarios
    Toninelli, C
    Wyart, M
    Berthier, L
    Biroli, G
    Bouchaud, JP
    [J]. PHYSICAL REVIEW E, 2005, 71 (04):
  • [27] Length scale of dynamic heterogeneities at the glass transition determined by multidimensional nuclear magnetic resonance
    Tracht, U
    Wilhelm, M
    Heuer, A
    Feng, H
    Schmidt-Rohr, K
    Spiess, HW
    [J]. PHYSICAL REVIEW LETTERS, 1998, 81 (13) : 2727 - 2730
  • [28] A heterogeneous picture of α relaxation for fragile supercooled liquids
    Viot, P
    Tarjus, G
    Kivelson, D
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2000, 112 (23) : 10368 - 10378
  • [29] WANG LM, 2003, J CHEM PHYS, V118, P10184
  • [30] Three-dimensional direct imaging of structural relaxation near the colloidal glass transition
    Weeks, ER
    Crocker, JC
    Levitt, AC
    Schofield, A
    Weitz, DA
    [J]. SCIENCE, 2000, 287 (5453) : 627 - 631