Thiacalixarenes as cluster keepers: synthesis and structural analysis of a magnetically coupled tetracopper(II) square

被引：112

作者：

Mislin, G

Graf, E

Hosseini, MW ^{[1
]}

Bilyk, A

Hall, AK

Harrowfield, JM

Skelton, BW

White, AH

机构：

[1] Univ Strasbourg 1, Chim Coordinat Organ Lab, CNRS, URA 422, F-67000 Strasbourg, France

[2] Univ Western Australia, Special Res Ctr Adv Minerals & Mat Proc, Nedlands, WA 6907, Australia

[3] Univ Western Australia, Crystallog Ctr, Nedlands, WA 6907, Australia

[4] Univ Western Australia, Dept Chem, Nedlands, WA 6907, Australia

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 04期

关键词：

D O I：

10.1039/a809184f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An X-ray structure determination of an antiferromagnetic copper complex of p-tert-butyltetrathiacalix[4]arene has shown it to contain a square, phenoxo- and sulfur-bridged cluster of four Cu(II) ions sandwiched between two fully deprotonated calixarenes, thus forming a ditopic, divergent receptor; as prepared, the complex has each cavity occupied by a molecule of dichloromethane.

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页码：373 / 374

页数：2

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