Ligand-free heck reaction:: Pd(OAc)2 as an active catalyst revisited

被引：250

作者：

Yao, QW ^{[1
]}

Kinney, EP

Yang, Z

机构：

[1] No Illinois Univ, Michael Faraday Labs, Dept Chem & Biochem, De Kalb, IL 60115 USA

[2] Shanxi Inst Chem Engn, Shanxi 030024, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 19期

关键词：

D O I：

10.1021/jo034646w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium acetate was shown to be an extremely active catalyst for the Heck reaction of aryl bromides. Both the base and the solvent were found to have a fundamental influence on the efficiency of the reaction, with K3PO4 and N,N-dimethylacetamide being the optimal base and solvent, respectively.

引用

页码：7528 / 7531

页数：4

共 68 条

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