Gold-catalyzed intermolecular Hetero-Dehydro-Diels-Alder cycloaddition of captodative dienynes with nitriles:: A new reaction and regioselective direct access to pyridines

被引：111

作者：

Barluenga, Jose ^{[1
]}

Fernandez-Rodriguez, Manuel Angel ^{[2
]}

Garcia-Garcia, Patricia ^{[1
]}

Aguilar, Enrique ^{[1
]}

机构：

[1] Univ Oviedo, Inst Univ Quim Organometal Enrique Moles, Unidad Asociada, CSIC, E-33006 Oviedo, Spain

[2] CSIC, Inst Invest Quim & Ambientales Barcelona, ES-08034 Barcelona, Spain

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 09期

关键词：

D O I：

10.1021/ja7112917

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For the first time, nitriles are used as 2 Pi electron component in a gold-catalyzed intermolecular Hetero-Dehydro-Diels-Alder cycloaddition with captodative enynes leading to the regioselective formation of pyridines.

引用

页码：2764 / +

页数：3

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