Chromium(0) alkynylcarbene complexes as Cβ-electrophilic carbene equivalents:: Regioselective access to dienynes and dienediynes

被引：34

作者：

Barluenga, Jose ^{[1
]}

Garcia-Garcia, Patricia ^{[1
]}

De Saa, Diana ^{[1
]}

Fernandez-Rodriguez, Manuel A. ^{[1
]}

de la Rua, Ramon Bernardo ^{[1
]}

Ballesteros, Alfredo ^{[1
]}

Aguilar, Enrique ^{[1
]}

Tomas, Miguel ^{[1
]}

机构：

[1] Univ Oviedo, CSIC, Inst Univ Quim Organomet Enrique Moles, Unidad Asociada, E-33006 Oviedo, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 15期

关键词：

carbenes; chromium; enynes; isomerization; olefination;

D O I：

10.1002/anie.200605197

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Just one step is all that is needed for a direct, selective, and easy synthesis of different conjugated enyne frameworks from simple chromium alkynylcarbene complexes and commercially available 2-methoxyfuran (see scheme). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2610 / 2612

页数：3

共 34 条

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