A new polycatenated 3D array of interlaced 2D brickwall layers and ID molecular ladders in [Mn2(bix)3(NO3)4]•2CHCl3 [bix=1,4-bis(imidazol-1-ylmethyl)benzene] that undergoes supramolecular isomerization upon guest removal

被引：99

作者：

Carlucci, Lucia ^{[1
]}

Ciani, Gianfranco ^{[1
]}

Maggini, Simona ^{[1
]}

Proserpio, Davide M. ^{[1
]}

机构：

[1] Univ Milan, Dipartmento Chim Strutturale & Stereochim Inorgan, I-20133 Milan, Italy

来源：

CRYSTAL GROWTH & DESIGN | 2008年 / 8卷 / 01期

关键词：

D O I：

10.1021/cg700884q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of Mn(II) nitrate with the flexible ligand 1,4-bis(imidazol-1-ylmethyl)benzene (bix) (reagent ratios 1:2-1:3) yield novel interesting coordination networks including, besides the ladder-like species [Mn(bix)(1.5)(NO3)(2)] and the 2-fold interpenetrated three-dimensional (3D) cds network [Mn(bix)(2)(NO3)(2)], the exceptional [Mn-2(bix)(3)(NO3)(4)]center dot 2CHCl(3), which is comprised of two different supramolecular isomers, namely, brickwall layers and one-dimensional (ID) molecular ladders, polycatenated to give a 3D (2D + 1D) architecture.

引用

页码：162 / 165

页数：4

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