The Interaction of Li+ with Single-Layer and Few-Layer Graphene

被引:339
作者
Pollak, Elad [1 ]
Geng, Baisong [2 ,3 ]
Jeon, Ki-Joon [1 ]
Lucas, Ivan T. [1 ]
Richardson, Thomas J. [1 ]
Wang, Feng [2 ,3 ]
Kostecki, Robert [1 ]
机构
[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Environm Energy Technol Div, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
[3] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA
关键词
graphene; lithium intercalation; CVD; Raman spectroscopy; LITHIUM; INTERCALATION; STORAGE;
D O I
10.1021/nl101223k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The interaction of Li+ with single and few layer graphene is reported. In situ Raman spectra were collected during the electrochemical lithiation of the single- and few-layer graphene. While the interaction of lithium with few layer graphene seems to resemble that of graphite, single layer graphene behaves very differently. The amount of lithium absorbed on single layer graphene seems to be greatly reduced due to repulsion forces between Li+ at both sides of graphene layer.
引用
收藏
页码:3386 / 3388
页数:3
相关论文
共 27 条
[21]   Intercalated nanographite: Structure and electronic properties [J].
Prasad, BLV ;
Sato, H ;
Enoki, T ;
Hishiyama, Y ;
Kaburagi, Y ;
Rao, AM ;
Sumanasekera, GU ;
Eklund, PC .
PHYSICAL REVIEW B, 2001, 64 (23)
[22]   Half-metallic graphene nanoribbons [J].
Son, Young-Woo ;
Cohen, Marvin L. ;
Louie, Steven G. .
NATURE, 2006, 444 (7117) :347-349
[23]   INFRARED AND RAMAN-SPECTROSCOPY OF GRAPHITE-FERRIC CHLORIDE [J].
UNDERHILL, C ;
LEUNG, SY ;
DRESSELHAUS, G ;
DRESSELHAUS, MS .
SOLID STATE COMMUNICATIONS, 1979, 29 (11) :769-774
[24]   Quantum hall effect in a gate-controlled p-n junction of graphene [J].
Williams, J. R. ;
DiCarlo, L. ;
Marcus, C. M. .
SCIENCE, 2007, 317 (5838) :638-641
[25]  
Yan J., 2007, PHYS REV LETT, V98
[26]   Large reversible Li storage of graphene nanosheet families for use in rechargeable lithium ion batteries [J].
Yoo, EunJoo ;
Kim, Jedeok ;
Hosono, Eiji ;
Zhou, Hao-shen ;
Kudo, Tetsuichi ;
Honma, Itaru .
NANO LETTERS, 2008, 8 (08) :2277-2282
[27]   Experimental observation of the quantum Hall effect and Berry's phase in graphene [J].
Zhang, YB ;
Tan, YW ;
Stormer, HL ;
Kim, P .
NATURE, 2005, 438 (7065) :201-204