Asymmetric allylation of aldehydes with allyltrichlorosilane promoted by chiral sulfoxides

被引：67

作者：

Massa, A

Malkov, AV

Kocovsky, P

Scettri, A

机构：

[1] Univ Salerno, Dipartimento Chim, I-84081 Baronissi, Salerno, Italy

[2] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 38期

关键词：

D O I：

10.1016/S0040-4039(03)01801-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allylation of aldehydes with allyltrichlorosilane in the presence of sulfoxides is reported. The use of excess of (R)-methyl-p-tolylsulfoxide resulted in the formation of the corresponding homoallylic alcohols in good yields and moderate enantiomeric excesses. (C) 2003 Elsevier Ltd. All rights reserved.

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页码：7179 / 7181

页数：3

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