Three-metal-center spin interactions through the intercalation of metal azaporphines and porphines into an organic pillared coordination box

被引：48

作者：

Ono, Kosuke ^{[1
]}

Yoshizawa, Michito ^{[1
,2
]}

Kato, Tatsuhisa ^{[3
]}

Fujita, Makoto ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

[2] Japan Sci & Technol Agcy, PRESTO, Tokyo, Japan

[3] Josai Univ, Fac Sci, Dept Chem, Sakado, Saitama 3500295, Japan

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 20期

关键词：

D O I：

10.1039/b801701h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Discrete homo Cu-Cu-Cu and hetero Cu-Pd-Cu or Cu-Co-Cu metal arrays are prepared within an organic-pillared coordination box by inserting M(II)-azaporphine/ porphine cartridges (M = Cu(II), Pd(II) or Co(II)), where the metal arrays show unique spin interactions in ESR: in particular, Delta m(s) = 3 for the Cu-Cu-Cu array.

引用

页码：2328 / 2330

页数：3

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