Waste-free and environment-friendly uncatalyzed synthesis of dithiocarbamates under solvent-free conditions

被引:55
作者
Azizi, Naimedin
Ebrahimi, Forogh
Aakbari, Elham
Aryanasab, Fezzeh
Saidi, Mohammad R. [1 ]
机构
[1] Sharif Univ Technol, Dept Chem, Tehran 11365, Iran
[2] Chem & Chem Engn Res Ctr, Tehran 14335, Iran
关键词
amines; dithiocarbamates; solvent-free; carbon disulfide; waste-free;
D O I
10.1055/s-2007-991085
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A mild, convenient, and practical one-pot procedure for the direct synthesis of dithiocarbamates has been developed by condensation of amines, CS2, and a Michael acceptor, under solvent-free conditions at room temperature in good to excellent yields.
引用
收藏
页码:2797 / 2800
页数:4
相关论文
共 35 条
[11]   LiClO4 accelerated Michael addition of amines to α,β-unsaturated olefins under solvent-free conditions [J].
Azizi, N ;
Saidi, MR .
TETRAHEDRON, 2004, 60 (02) :383-387
[12]   Lithium perchlorate-catalyzed three-component coupling:: A facile and general method for the synthesis of α-aminophosphonates under solvent-free conditions [J].
Azizi, N ;
Saidi, MR .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 2003 (23) :4630-4633
[13]   Efficient Friedel-Crafts alkylation of indoles and pyrrole with enones and nitroalkene in water [J].
Azizi, Najmedin ;
Arynasab, Fezzeh ;
Saidi, Mohammad R. .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2006, 4 (23) :4275-4277
[14]   Synthesis of F-alkyl N-sulfonyl carbamates and thiocarbamates [J].
Beji, M ;
Sbihi, H ;
Baklouti, A ;
Cambon, A .
JOURNAL OF FLUORINE CHEMISTRY, 1999, 99 (01) :17-24
[15]   Determination of dithiocarbamate fungicide residues in food by a spectrophotometric method using a vertical disulfide reaction system [J].
Caldas, ED ;
Conceiçao, MH ;
Miranda, MCC ;
de Souza, LCKR ;
Lima, JF .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2001, 49 (10) :4521-4525
[16]   Magnesium bistrifluoromethanesulfonimide as a new and efficient acylation catalyst [J].
Chakraborti, Asit K. ;
Shivani .
JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (15) :5785-5788
[17]   S-CHLOROALLYL THIOCARBAMATE HERBICIDES - MOUSE HEPATIC MICROSOMAL L LYSOGENASE AND RAT-METABOLISM OF CIS-[C-14=O]DIALLATE AND TRANS-O]DIALLATE-C-14 [J].
CHEN, YS ;
SCHUPHAN, I ;
CASIDA, JE .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1979, 27 (04) :709-712
[18]  
Elgemeie GH, 2001, SYNTHESIS-STUTTGART, P1747
[19]   The chemistry of thiocyanic esters [J].
Erian, AW ;
Sherif, SM .
TETRAHEDRON, 1999, 55 (26) :7957-8024
[20]   Conjugated addition reaction of amine, carbon disulfide to electrophilic alkenes in the presence of anhydrous potassium phosphate [J].
Guo, BG ;
Ge, ZM ;
Cheng, TM ;
Li, RT .
SYNTHETIC COMMUNICATIONS, 2001, 31 (19) :3021-3025