An EPR study of the intramolecular dynamics in o-semiquinonic nickel complexes with a diphosphorous pincer ligand

被引：30

作者：

Kozhanov, KA ^{[1
]}

Bubnov, MP ^{[1
]}

Cherkasov, VK ^{[1
]}

Fukin, GK ^{[1
]}

Abakumov, GA ^{[1
]}

机构：

[1] Russian Acad Sci, GA Razuvaev Inst Organomet Chem, Nizhnii Novgorod 603950, Russia

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 20期

关键词：

D O I：

10.1039/b308701h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Square pyramidal o-semiquinonic nickel complexes with 2,6-bis( diphenylphosphinomethyl) phenyl have a flexible coordination sphere and exist in solution as the mixture of tautomers rapidly, according to EPR time scale, interconverting at room temperature.

引用

页码：2610 / 2611

页数：2

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