Temperature- and stoichiometry-controlled dimensionality in a magnesium 4,5-imidazoledicarboxylate system with strong hydrophilic pore surfaces

被引:125
作者
Gurunatha, K. L. [1 ]
Uemura, Kazuhiro [2 ]
Maji, Tapas Kumar [1 ]
机构
[1] Indian Inst Sci, Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India
[2] Yamaguchi Univ, Grad Sch Sci & Engn, Ube, Yamaguchi 7558611, Japan
关键词
D O I
10.1021/ic8007377
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
1D, 2D, and 3D three metal-organic hybrid frameworks of Mg-II have been synthesized using 4,5-imidazoledicarboxylic acid (H(3)idc) with control of the temperature and stoichiometry in a hydrothermal technique. All of the frameworks show high thermal stability, and frameworks 1D and 3D provide highly hydrophilic pore surfaces, correlated by the selective sorption of water molecules over the organic vapor and other gases like N-2 and CO2,
引用
收藏
页码:6578 / 6580
页数:3
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