Work function independent hole-injection barriers between pentacene and conducting polymers

被引:117
作者
Koch, N
Elschner, A
Rabe, JP
Johnson, RL
机构
[1] Humboldt Univ, Inst Phys, D-12489 Berlin, Germany
[2] Bayer AG, HC Starck GmbH, D-51368 Leverkusen, Germany
[3] Univ Hamburg, Inst Expt Phys, D-22761 Hamburg, Germany
关键词
D O I
10.1002/adma.200400697
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The energy level alignment (see Figure) at interfaces between pentacene and thin films of conducting polymers (made from ethylenedioxythiophene and sulfonate moieties) is found to be independent of initial polymer work function or morphology. Interfacial chemical reactions control the energy level alignment, rather than just the pristine substrate work function.
引用
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页码:330 / +
页数:7
相关论文
共 29 条
[1]   Structure of thin films of poly(3,4-ethylenedioxythiophene) [J].
Aasmundtveit, KE ;
Samuelsen, EJ ;
Pettersson, LAA ;
Inganäs, O ;
Johansson, T ;
Feidenhans, R .
SYNTHETIC METALS, 1999, 101 (1-3) :561-564
[2]   Exchangelike effects for closed-shell adsorbates:: Interface dipole and work function -: art. no. 096104 [J].
Bagus, PS ;
Staemmler, V ;
Wöll, C .
PHYSICAL REVIEW LETTERS, 2002, 89 (09) :961041-961044
[3]   Hole injection from an ITO|PEDT anode into the hole transporting layer of an OLED probed by bias induced absorption [J].
Book, K ;
Bässler, H ;
Elschner, A ;
Kirchmeyer, S .
ORGANIC ELECTRONICS, 2003, 4 (04) :227-232
[4]   Conductivity, morphology, interfacial chemistry, and stability of poly(3,4-ethylene dioxythiophene)-poly(styrene sulfonate): A photoelectron spectroscopy study [J].
Crispin, X ;
Marciniak, S ;
Osikowicz, W ;
Zotti, G ;
Van der Gon, AWD ;
Louwet, F ;
Fahlman, M ;
Groenendaal, L ;
De Schryver, F ;
Salaneck, WR .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2003, 41 (21) :2561-2583
[5]   Characterization of the interface dipole at organic/metal interfaces [J].
Crispin, X ;
Geskin, V ;
Crispin, A ;
Cornil, J ;
Lazzaroni, R ;
Salaneck, WR ;
Brédas, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (27) :8131-8141
[6]   Low-cost all-polymer integrated circuits [J].
Drury, CJ ;
Mutsaers, CMJ ;
Hart, CM ;
Matters, M ;
de Leeuw, DM .
APPLIED PHYSICS LETTERS, 1998, 73 (01) :108-110
[7]   PEDT/PSS for efficient hole-injection in hybrid organic light-emitting diodes [J].
Elschner, A ;
Bruder, F ;
Heuer, HW ;
Jonas, F ;
Karbach, A ;
Kirchmeyer, S ;
Thurm, S .
SYNTHETIC METALS, 2000, 111 :139-143
[8]  
GRECZYNSKI G, 2003, J ELECT SPECTROSC RE, V121, P1
[9]  
Groenendaal BL, 2000, ADV MATER, V12, P481, DOI 10.1002/(SICI)1521-4095(200004)12:7<481::AID-ADMA481>3.0.CO
[10]  
2-C