Low-cost deposition of CuInSe2 (CIS) films for CdS/CIS solar cells

被引:26
作者
Hermann, AM [1 ]
Westfall, R [1 ]
Wind, R [1 ]
机构
[1] Univ Colorado, Superconduct Labs, Dept Phys, Boulder, CO 80309 USA
关键词
thin film; solar cells; CuInSe2; CIS;
D O I
10.1016/S0927-0248(97)00250-X
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
We discuss in this paper the development of inexpensive, high efficiency, large-area solar cells of the type thin-film ZnO/CdS/Cu(In,Ga)Se-2. It has been shown recently in research laboratory tests that polycrystalline thin-film cells of this general composition deposited onto inexpensive soda-lime glass substrates have solar-to-electric conversion efficiencies exceeding 17%. These small-area cells were deposited using vacuum technology which is difficult and expensive to scale up in area to square-meter flat-plate modules in a manufacturing arena. We discuss in this paper inexpensive, non-vacuum deposition technology which is inherently scalable to large-area deposition. We pay particular attention to electrodeposition of multilayer binary or ternary selenide precursors to be thermally annealed to form Cu(In,Ga)Se-2 films of appropriate overall composition, elemental grading and smoothness. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:355 / 360
页数:6
相关论文
共 11 条
[1]   Electrodeposition of In-Se, Cu-Se, and Cu-In-Se thin films [J].
Bhattacharya, RN ;
Fernandez, AM ;
Contreras, MA ;
Keane, J ;
Tennant, AL ;
Ramanathan, K ;
Tuttle, JR ;
Noufi, RN ;
Hermann, AM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (03) :854-858
[2]  
DIMMLER B, 1996, IN PRESS P 25 PHOT S
[3]   An 8% CuInSe2-based solar cell formed from an electrodeposited precursor film [J].
Fernandez, AM ;
Sebastian, PJ ;
Bhattacharya, RN ;
Noufi, R ;
Contreras, M ;
Hermanns, AM .
SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 1996, 11 (06) :964-967
[4]  
FULLOP G, 1982, APPL PHYS LETT, V40, P327
[5]   HIGH-EFFICIENCY CUINXGA1-XSE2 SOLAR-CELLS MADE FROM (INX,GA1-X)2SE3 PRECURSOR FILMS [J].
GABOR, AM ;
TUTTLE, JR ;
ALBIN, DS ;
CONTRERAS, MA ;
NOUFI, R ;
HERMANN, AM .
APPLIED PHYSICS LETTERS, 1994, 65 (02) :198-200
[6]   One, step electrodeposition of CuInSe2: Improved structural, electronic, and photovoltaic properties by annealing under high selenium pressure [J].
Guillemoles, JF ;
Cowache, P ;
Lusson, A ;
Fezzaa, K ;
Boisivon, F ;
Vedel, J ;
Lincot, D .
JOURNAL OF APPLIED PHYSICS, 1996, 79 (09) :7293-7302
[7]  
STONE JL, 1993, PHYS TODAY SEP, P22
[8]   17.1-PERCENT EFFICIENT CU(IN,GA)SE-2- BASED THIN-FILM SOLAR-CELL [J].
TUTTLE, JR ;
CONTRERAS, MA ;
GILLESPIE, TJ ;
RAMANATHAN, KR ;
TENNANT, AL ;
KEANE, J ;
GABOR, AM ;
NOUFI, R .
PROGRESS IN PHOTOVOLTAICS, 1995, 3 (04) :235-238
[9]  
WOODCOCK JM, 1994, P 12 EUR PHOT SOL EN, P948
[10]   THIN-FILMS - PAST, PRESENT, FUTURE [J].
ZWEIBEL, K .
PROGRESS IN PHOTOVOLTAICS, 1995, 3 (05) :279-293