Desymmetrization of meso-1,2-diols via chiral oxazaborolidine-mediated ring-cleavage of acetal derivatives with silyl ketene S,O-acetal

被引：30

作者：

Kinugasa, M ^{[1
]}

Harada, T ^{[1
]}

Oku, A ^{[1
]}

机构：

[1] Kyoto Inst Technol, Dept Chem, Sakyo Ku, Matsugasaki 606, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 25期

关键词：

acetals; diols; asymmetric induction; amino alcohols;

D O I：

10.1016/S0040-4039(98)00823-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Desymmetrization of meso-1,2-diols leading to enantiomerically enriched MOM and MEM ethers is realized via chiral oxazaborolidine-mediated enantioselective ring-cleavage reaction of the acetal derivatives with silyl ketene S,O-acetal. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：4529 / 4532

页数：4

共 21 条

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