A novel, more vivid Cu2Zn2SOD model: Crystal structure and some properties of the Schiff base copper(II) complex: [Cu(appn)] (ClO4)(2)center dot H2O

被引：48

作者：

Liu, CM

Xiong, RG

You, XA

Fun, HK

Sivakumar, K

机构：

[1] NANJING UNIV,STATE KEY LAB COORDINAT CHEM,INST COORDINAT CHEM,NANJING 210093,PEOPLES R CHINA

[2] UNIV SAINS MALAYSIA,SCH PHYS,XRAY CRYSTALLOG UNIT,GEORGE TOWN 11800,MALAYSIA

来源：

POLYHEDRON | 1997年 / 16卷 / 01期

关键词：

D O I：

10.1016/0277-5387(96)00216-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel Cu,Zn, superoxide dismutase (Cu2Zn2SOD) mimic compound [Cu(appn)](ClO4)(2) . H2O [where appn = N,N'-propylenebis(2-actoylpyridineiminato)] has been prepared. Single-crystal X-ray analysis revealed that the copper(II) ion has a distorted square-pyramidal environment very similar to that of Cu2Zn2SOD: the basal positions are occupied by four nitrogen atoms from the Schiff base ligand and the apical position by an oxygen atom of a hydrate molecule. The Cu-N and Cu-O bond lengths are 1.972(2)... 2.029(2) and 2.326(2)Angstrom, respectively. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：119 / 123

页数：5

共 13 条

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