Oxidations catalysed by rhenium(V) oxides 2. Clean sulfide oxidation by urea hydrogen peroxide

被引：49

作者：

Gunaratne, HQN

McKervey, MA ^{[1
]}

Feutren, S

Finlay, J

Boyd, J

机构：

[1] Queens Univ Belfast, QUESTOR Ctr, Belfast BT9 5AG, Antrim, North Ireland

[2] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 31期

关键词：

D O I：

10.1016/S0040-4039(98)01100-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three rhenium(V) oxo phosphine complexes and methyltrioxorhenium have been used as catalysts for oxidation of sulfides to sulfoxides with urea-hydrogen peroxide as oxidant in acetonitrile; partial enantioselective oxidation of methylphenyl sulfide was observed with methyltrioxorhenium in the presence of a (+)-camphor derived pyrazine carboxylic acid. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：5655 / 5658

页数：4

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