The 8 : 1 : 1 ternary hybrid framework in the system [EDT-TTF•+][1,4-bis(iodoethynyl)benzene][Re6Se8(CN)6]4-:: dual noncovalent expression of the octahedral halogen-bond hexa-acceptor nanonode

被引：30

作者：

Barres, Anne-Lise ^{[1
]}

El-Ghayoury, Abdelkrim ^{[1
]}

Zorina, Leokadiya V. ^{[1
]}

Canadell, Enric ^{[2
]}

Auban-Senzier, Pascale ^{[3
]}

Batail, Patrick ^{[1
]}

机构：

[1] Univ Angers, CNRS, Lab Chim Ingn Mol & Mat Angers, F-49045 Angers, France

[2] Inst Ciencia Mat Barcelona ICMAB CSIC, E-08193 Barcelona, Spain

[3] Univ Paris 11, Phys Solides Lab, F-91405 Orsay, France

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 19期

关键词：

D O I：

10.1039/b800571k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complementary shapes of the neutral symmetrical halogen-bond bis-donor core and octahedral inorganic cluster core prevent halogen-bonded polymers developing in more than one direction, favouring further templating by conducting radical cation slabs and yielding an 8 : 1 : 1 phase formulation instead of n : 2 : 1, with a 2D net, or m : 3 : 1, with a pseudo-cubic architecture, which may in principle also be targeted.

引用

页码：2194 / 2196

页数：3

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