Jahn-Teller distortion of the open-shell 23-electron chalcogenide rhenium cluster cores in crystals of the series, {[Re6Q8]3+(X-)6}3- (Q = S, Se; X = Cl, CN)

被引：40

作者：

Baudron, SA ^{[1
]}

Deluzet, A ^{[1
]}

Boubekeur, K ^{[1
]}

Batail, P ^{[1
]}

机构：

[1] Univ Angers, CNRS, FRE 2447, Chim Organ Lab, Angers, France

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 18期

关键词：

D O I：

10.1039/b205241e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Comparison within the title [Re(6)Q(8)X(6)](4-)/[Re(6)Q(8)X(6)](3-) redox series of 14 precise crystal structures of the Re-6 cluster cores at different low temperatures reveals that the one-electron oxidised, open-shell (23 electron) cores undergo a Jahn-Teller distortion of their parent 24 electron octahedral cores and that D-4h and D-2h forms may co-exist in the solid state.

引用

页码：2124 / 2125

页数：2

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