Jahn-Teller distortion of the open-shell 23-electron chalcogenide rhenium cluster cores in crystals of the series, {[Re6Q8]3+(X-)6}3- (Q = S, Se; X = Cl, CN)

被引:40
作者
Baudron, SA [1 ]
Deluzet, A [1 ]
Boubekeur, K [1 ]
Batail, P [1 ]
机构
[1] Univ Angers, CNRS, FRE 2447, Chim Organ Lab, Angers, France
关键词
D O I
10.1039/b205241e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Comparison within the title [Re(6)Q(8)X(6)](4-)/[Re(6)Q(8)X(6)](3-) redox series of 14 precise crystal structures of the Re-6 cluster cores at different low temperatures reveals that the one-electron oxidised, open-shell (23 electron) cores undergo a Jahn-Teller distortion of their parent 24 electron octahedral cores and that D-4h and D-2h forms may co-exist in the solid state.
引用
收藏
页码:2124 / 2125
页数:2
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