Effects of microstructure in ethylene glycol oxidation on graphite supported platinum electrodes

被引：21

作者：

Lebedeva, NP ^{[1
]}

Kryukova, GN ^{[1
]}

Tsybulya, SV ^{[1
]}

Salanov, AN ^{[1
]}

Savinova, ER ^{[1
]}

机构：

[1] RAS, SB, Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

ELECTROCHIMICA ACTA | 1998年 / 44卷 / 8-9期

关键词：

electrooxidation; ethylene glycol; Pt; graphite-supported platinum; structural effects;

D O I：

10.1016/S0013-4686(98)00266-7

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Activities of graphite supported and polycrystalline Pt in electrocatalytic oxidation of ethylene glycol in neutral unbuffered Na2SO4 solutions have been compared. Morphology and microstructure of supported Pt electrodes have been studied using scanning electron microscopy, high-resolution transmission electron microscopy and X-ray diffraction. Specific activity of Pt electrodes and sensitivity to poisoning has been found to depend strongly on their microstructure. Supported electrodes appear to be from four to six times less active than polycrystalline PI in the potential region between 0.3 and 0.9 V vs. SHE but much more stable to self-poisoning. The electrode microstructure has much less effect on the activity at high (over 0.9 V vs. SHE) anodic potentials. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1431 / 1440

页数：10

共 48 条

[11] THE INTERCONVERSION OF ADSORBED METHANOL FRAGMENTS ON PLATINUM AT CATHODIC POTENTIALS
CHRISTENSEN, PA
HAMNETT, A
POTTER, RJ
[J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1990, 94 (09): : 1034 - 1038
[12] AN IN-SITU FTIR STUDY OF THE ELECTROCHEMICAL OXIDATION OF METHANOL AT SMALL PLATINUM PARTICLES
CHRISTENSEN, PA
HAMNETT, A
MUNK, J
TROUGHTON, GL
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 370 (1-2): : 251 - 258
[13] DICENZO SB, 1994, SPRINGER SERIES CHEM, V56, P360
[14] ELECTROCHEMICAL STUDIES IN SULFURIC-ACID-SOLUTIONS OF ABSORBED CO ON PT (111) ELECTRODES
FELIU, JM
ORTS, JM
FERNANDEZVEGA, A
ALDAZ, A
CLAVILIER, J
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 296 (01): : 191 - 201
[15] THE 3RD ANODIC HYDROGEN PEAK ON PLATINUM - SUBSURFACE H-2 ADSORPTION
FRELINK, T
VISSCHER, W
VANVEEN, JAR
[J]. ELECTROCHIMICA ACTA, 1995, 40 (05) : 545 - 549
[16] Gleiter H., 1992, Nanostructured Materials, V1, P1, DOI 10.1016/0965-9773(92)90045-Y
[17] SMALL-PARTICLE RESEARCH - PHYSICOCHEMICAL PROPERTIES OF EXTREMELY SMALL COLLOIDAL METAL AND SEMICONDUCTOR PARTICLES
HENGLEIN, A
[J]. CHEMICAL REVIEWS, 1989, 89 (08) : 1861 - 1873
[18] INZELT G, 1979, ACTA CHIM HUNG, V101, P229
[19] ELECTROOXIDATION OF ETHYLENE-GLYCOL ON BISMUTH-MODIFIED PT(111)
JIANG, XD
CHANG, SC
WEAVER, MJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (02): : 223 - 228
[20] KHRUSHCHEVA ML, 1994, ELEKTROKHIMIYA, V30, P755

← 1 2 3 4 5 →