Band-Like Electron Transport in Organic Transistors and Implication of the Molecular Structure for Performance Optimization

被引:252
作者
Minder, Nikolas A. [2 ,3 ]
Ono, Shimpei [2 ,3 ,4 ]
Chen, Zhihua [1 ]
Facchetti, Antonio [1 ,5 ,6 ]
Morpurgo, Alberto F. [2 ,3 ]
机构
[1] Polyera Corp, Skokie, IL 60077 USA
[2] Univ Geneva, DPMC, CH-1211 Geneva, Switzerland
[3] Univ Geneva, GAP, CH-1211 Geneva, Switzerland
[4] Cent Res Inst Elect Power Ind, Tokyo 2018511, Japan
[5] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[6] Northwestern Univ, Mat Res Ctr, Evanston, IL 60208 USA
基金
瑞士国家科学基金会;
关键词
organic single-crystal; field-effect transistor; n-type; Hall effect; band-like transport; FIELD-EFFECT TRANSISTORS; SINGLE-CRYSTAL TRANSISTORS; CHARGE-TRANSPORT; N-TYPE; GATE DIELECTRICS; THIN-FILMS; SEMICONDUCTORS; MOBILITY; STABILITY; CIRCUITS;
D O I
10.1002/adma.201103960
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Hall effect and an increase of field-effect mobility with decreasing temperature is observerd in n-channel single-crystal organic field-effect transistors (OFETs). A quantitative analysis of these findings, together with results on different p-channel transistors, indicate the importance of the semiconductor molecular polarizability and the structure of the charge transport layers in the crystal for the observation of band-like transport in OFETs.
引用
收藏
页码:503 / +
页数:7
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