Supramolecular isomerism with polythreaded topology based on [Mo8O26]4- isomers

被引：155

作者：

Lan, Ya-Qian ^{[1
]}

Li, Shun-Li ^{[1
]}

Wang, Xin-Long ^{[1
]}

Shao, Kui-Zhan ^{[1
]}

Su, Zhong-Min ^{[1
]}

Wang, En-Bo ^{[1
]}

机构：

[1] NE Normal Univ, Fac Chem, Minist Educ, Inst Funct Mat Chem,Key Lab Polyoxomet Sci, Changchun 130024, Peoples R China

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 02期

关键词：

D O I：

10.1021/ic701463h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two compounds, namely, [Cu(bbi)](2)[Cu-2(bbi)(2)(delta-Mo8O26)(0.5)][alpha-Mo8O26](0.5) (1) and [Cu(bbi)][Cu(bbi)(theta-Mo8O26)(0.5)] (2), where bbi is 1,1 '-(1,4-butanediyl)bis(imidazole), were synthesized under hydrothermal conditions at different pH values. Their crystal structures were determined by X-ray diffraction. Compounds 1 and 2 are supramolecular isomers with a polythreaded topology based on octamolybdate building blocks.

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页码：529 / 534

页数：6

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