Supramolecular isomerism with polythreaded topology based on [Mo8O26]4- isomers

被引：155

作者：

Lan, Ya-Qian ^{[1
]}

Li, Shun-Li ^{[1
]}

Wang, Xin-Long ^{[1
]}

Shao, Kui-Zhan ^{[1
]}

Su, Zhong-Min ^{[1
]}

Wang, En-Bo ^{[1
]}

机构：

[1] NE Normal Univ, Fac Chem, Minist Educ, Inst Funct Mat Chem,Key Lab Polyoxomet Sci, Changchun 130024, Peoples R China

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 02期

关键词：

D O I：

10.1021/ic701463h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two compounds, namely, [Cu(bbi)](2)[Cu-2(bbi)(2)(delta-Mo8O26)(0.5)][alpha-Mo8O26](0.5) (1) and [Cu(bbi)][Cu(bbi)(theta-Mo8O26)(0.5)] (2), where bbi is 1,1 '-(1,4-butanediyl)bis(imidazole), were synthesized under hydrothermal conditions at different pH values. Their crystal structures were determined by X-ray diffraction. Compounds 1 and 2 are supramolecular isomers with a polythreaded topology based on octamolybdate building blocks.

引用

页码：529 / 534

页数：6

共 87 条

[11] The electronic structure and stability of the isomers of octamolybdate [J].

Bridgeman, AJ .

JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (50) :12151-12160

[12] A neutral 3D copper coordination polymer showing 1D open channels and the first interpenetrating NbO-type network [J].

Bu, XH ;

Tong, ML ;

Chang, HC ;

Kitagawa, S ;

Batten, SR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (02) :192-195

[13] A new type of supramolecular entanglement in the silver(I) coordination polymer [Ag2(bpethy)5](BF4)2 [bpethy = 1,2-bis(4-pyridyl)ethyne] [J].

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

CHEMICAL COMMUNICATIONS, 1999, (05) :449-450

[14] Polycatenation, polythreading and polyknotting in coordination network chemistry [J].

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :247-289

[15] Borromean links and other non-conventional links in 'polycatenated' coordination polymers: re-examination of some puzzling networks [J].

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

CRYSTENGCOMM, 2003, 5 :269-279

[16]

Che CM, 2000, ANGEW CHEM INT EDIT, V39, P4084, DOI 10.1002/1521-3773(20001117)39:22<4084::AID-ANIE4084>3.3.CO

[17]

2-E

[18] Solvothermal in situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry [J].

Chen, Xiao-Ming ;

Tong, Ming-Liang .

ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (02) :162-170

[19] Interpenetrating copper-silver cyanometallate networks: Polymorphs and topological isomers [J].

Chippindale, AM ;

Cheyne, SM ;

Hibble, SJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (48) :7942-7946

[20] Polyoxometalate-based molecular materials [J].

Coronado, E ;

Gomez-Garcia, CJ .

CHEMICAL REVIEWS, 1998, 98 (01) :273-296

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