Reduced graphene oxide as a catalyst for hydrogenation of nitrobenzene at room temperature

被引：394

作者：

Gao, Yongjun ^{[1
]}

Ma, Ding ^{[1
]}

Wang, Chunlei ^{[1
]}

Guan, Jing ^{[1
]}

Bao, Xinhe ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 08期

关键词：

GRAPHITE OXIDE; REDUCTION; NANOSHEETS; HYDRAZINE; STATE;

D O I：

10.1039/c0cc04420b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduced graphene oxide was used as a catalyst for reduction of nitrobenzene at room temperature. High catalytic activity and stability were exhibited in circular experiments. The catalytic procedure was in situ monitored by NMR and N-phenylhydroxylamine was proved to be the intermediate in this catalytic reaction.

引用

页码：2432 / 2434

页数：3

共 22 条

[1] Synthesis and solid-state NMR structural characterization of 13C-labeled graphite oxide [J].

Cai, Weiwei ;

Piner, Richard D. ;

Stadermann, Frank J. ;

Park, Sungjin ;

Shaibat, Medhat A. ;

Ishii, Yoshitaka ;

Yang, Dongxing ;

Velamakanni, Aruna ;

An, Sung Jin ;

Stoller, Meryl ;

An, Jinho ;

Chen, Dongmin ;

Ruoff, Rodney S. .

SCIENCE, 2008, 321 (5897) :1815-1817

[2] Electronic structures of graphene edges and nanographene [J].

Enoki, Toshiaki ;

Kobayashi, Yousuke ;

Fukui, Ken-Ichi .

INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY, 2007, 26 (04) :609-645

[3] A study of nitrobenzene hydrogenation over palladium/carbon catalysts [J].

Gelder, EA ;

Jackson, SD ;

Lok, CM .

CATALYSIS LETTERS, 2002, 84 (3-4) :205-208

[4]

HAN BH, 1985, TETRAHEDRON LETT, V26, P6233

[5] Unique chemical reactivity of a graphene nanoribbon's zigzag edge [J].

Jiang, De-en ;

Sumpter, Bobby G. ;

Dai, Sheng .

JOURNAL OF CHEMICAL PHYSICS, 2007, 126 (13)

[6] From armchair to zigzag peripheries in nanographenes [J].

Kastler, Marcel ;

Schmidt, Jochen ;

Pisula, Wojciech ;

Sebastiani, Daniel ;

Muellen, Klaus .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (29) :9526-9534

[7] Edge state on hydrogen-terminated graphite edges investigated by scanning tunneling microscopy [J].

Kobayashi, Y ;

Fukui, K ;

Enoki, T ;

Kusakabe, K .

PHYSICAL REVIEW B, 2006, 73 (12)

[8] Selective Aerobic Oxidation of Benzylic Alcohols Catalyzed by Carbon-Based Catalysts: A Nonmetallic Oxidation System [J].

Kuang, Yongbo ;

Islam, Nazrul M. ;

Nabae, Yuta ;

Hayakawa, Teruaki ;

Kakimoto, Masa-aki .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (02) :436-440

[9] Mechanism of the carbon catalyzed reduction of nitrobenzene by hydrazine [J].

Larsen, JW ;

Freund, M ;

Kim, KY ;

Sidovar, M ;

Stuart, JL .

CARBON, 2000, 38 (05) :655-661

[10] Electronic structures of zigzag graphene nanoribbons with edge hydrogenation and oxidation [J].

Lee, Geunsik ;

Cho, Kyeongjae .

PHYSICAL REVIEW B, 2009, 79 (16)

← 1 2 3 →