Complexes of heteroscorpionate trispyrazolylborate ligands.: Part XI.: Weak CH/π interactions in crystals of hydrotris(3-phenylpyrazolyl) boratothallium(I) and hydrobis(5-methyl-3-phenylpyrazolyl)(3,5-dimethylpyrazol-yl)boratothallium(I) studied by X-ray crystallography

被引：32

作者：

Ciunik, Z

Ruman, T

Lukasiewicz, M

Wolowiec, S

机构：

[1] Rzeszow Univ Technol, Fac Chem, PL-35959 Rzeszow, Poland

[2] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2004年 / 690卷 / 1-3期

关键词：

trispyrazolylboratothallium complexes; structures; CH/pi interaction;

D O I：

10.1016/j.molstruc.2003.12.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Thallium(I) complexes of heteroscorpionate hydrobis(3-phenyl-5-methylpyrazolyl)(3,5-dimethylpyrazol-yl)borate and hydrotris(3-phenylpyrazol-1-yl)borate were studied crystallographically. Both ligands were coordinated in kappa(3) fashion via N-2 atoms of pyrazol-1-yl moieties. Both compounds crystallize as centrosymmetric dimers in which weak CH/pi intra- and interdimer interactions are responsible for arrangement in crystal structure. (C) 2003 Elsevier B.V. All fights reserved.

引用

收藏

页码：175 / 180

页数：6

相关论文

共 51 条

[1] CRYSTAL-STRUCTURES OF SILVER(I) AND THALLIUM(I) COMPLEXES OF TRIS[3-(2-PYRIDYL)-PYRAZOL-1-YL]BORATE - ENCAPSULATION OF EITHER A SINGLE THALLIUM(I) ION OR TRINUCLEAR SILVER(I) CLUSTER BY A HEXADENTATE PODAND [J].

AMOROSO, AJ ;

JEFFERY, JC ;

JONES, PL ;

MCCLEVERTY, JA ;

PSILLAKIS, E ;

WARD, MD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (11) :1175-1176

[2] Syntheses and characterization of hydrotris(1-pyrazolyl)borate dihydrogen complexes of ruthenium and their roles in catalytic hydrogenation reactions [J].

Chan, WC ;

Lau, CP ;

Chen, YZ ;

Fang, YQ ;

Ng, SM ;

Jia, GC .

ORGANOMETALLICS, 1997, 16 (01) :34-44

[3] HYDRIDOTRIS(3-T-BUTYLPYRAZOLYL)BORATOTHALLIUM(I) - A SPECTROSCOPIC AND STRUCTURAL STUDY [J].

COWLEY, AH ;

GEERTS, RL ;

NUNN, CM ;

TROFIMENKO, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 365 (1-2) :19-22

[4] Thallium(I) complexes with modified poly(pyrazolyl)borate ligands - metal-ligand coordination and crystal packing [J].

Craven, E ;

Mutlu, E ;

Lundberg, D ;

Temizdemir, S ;

Dechert, S ;

Brombacher, H ;

Janiak, C .

POLYHEDRON, 2002, 21 (5-6) :553-562

[5] STRUCTURE OF HYDRIDOTRIS[3-(PARA-TOLYL)PYRAZOLYL]BORATOTHALLIUM(I) [J].

FERGUSON, G ;

JENNINGS, MC ;

LALOR, FJ ;

SHANAHAN, C .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :2079-2082

[6] Bis- and tris(pyrazolyl)hydroborato ligands with bulky triptycyl substituents: The synthesis and structural characterization of Tl[Bp(Trip)] and Tl[Tp(Trip)] [J].

Fillebeen, T ;

Hascall, T ;

Parkin, G .

INORGANIC CHEMISTRY, 1997, 36 (17) :3787-&

[7] EFFICIENT AND SELECTIVE CARBON-HYDROGEN ACTIVATION BY A TRIS(PYRAZOLYL)BORATE RHODIUM COMPLEX [J].

GHOSH, CK ;

GRAHAM, WAG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (15) :4726-4727

[8] Synthesis and molecular structure of bis(pyrazolyl)(3,5-di-tert-butylpyrazolyl)hydroborato thallium:: a hetero-tris(pyrazolyl)hydroborato ligand derived from two different pyrazoles [J].

Ghosh, P ;

Churchill, DG ;

Rubinshtein, M ;

Parkin, G .

NEW JOURNAL OF CHEMISTRY, 1999, 23 (10) :961-963

[9] Vinylic C-H bond activation and hydrogenation reactions of Tp′Ir(C2H4)(L) complexes [J].

Gutierrez-Puebla, E ;

Monge, A ;

Nicasio, MC ;

Perez, PJ ;

Poveda, ML ;

Rey, L ;

Ruiz, C ;

Carmona, E .

INORGANIC CHEMISTRY, 1998, 37 (18) :4538-4546

[10] Synthesis and structural characterization of tris[3-trifluoromethyl-5-(2-thienyl)pyrazolyl]hydroborato thallium, Tl[Tp(CF3,Tn)]: A monovalent thallium complex with a highly solvent dependent J(Tl-F) coupling constant, ranging from 0 to 850 Hz [J].

Han, R ;

Ghosh, P ;

Desrosiers, PJ ;

Trofimenko, S ;

Parkin, G .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (20) :3713-3717

← 1 2 3 4 5 6 →