Microporous Hybrid Polymer with a Certain Crystallinity Built from Functionalized Cubic Siloxane Cages as a Singular Building Unit

被引:83
作者
Chaikittisilp, Watcharop [1 ]
Sugawara, Ayae [1 ]
Shimojima, Atsushi [1 ]
Okubo, Tatsuya [1 ]
机构
[1] Univ Tokyo, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan
关键词
HIGH-SURFACE-AREA; ORGANIC FRAMEWORKS; HYDROGEN STORAGE; POROUS MATERIALS; NETWORKS; BLOCKS; DESIGN; CHEMISTRY; ZEOLITES;
D O I
10.1021/cm1017882
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Microporous inorganic-organic hybrid with high surface area and large pore volume has been synthesized from bromophenylethenyl-terminated double four-ring (D4R) siloxane cages as a single precursor. Unprecedentedly, the resulting hybrid possesses preferential long-range order and uniform micropore size distribution. In addition, D4R cages have been proven to be retained in the networks after the reaction. © 2010 American Chemical Society.
引用
收藏
页码:4841 / 4843
页数:3
相关论文
共 33 条
  • [1] Structural investigation of encapsulated fluoride in polyhedral oligomeric silsesquioxane cages using ion mobility mass spectrometry and molecular mechanics
    Anderson, Stanley E.
    Bodzin, Dena J.
    Haddad, Timothy S.
    Boatz, Jerry A.
    Mabry, Joseph M.
    Mitchell, Connie
    Bowers, Michael T.
    [J]. CHEMISTRY OF MATERIALS, 2008, 20 (13) : 4299 - 4309
  • [2] Chemistry of hydrogen-octasilsesquioxane: Preparation and characterization of octasilsesquioxane-containing polymers
    Auner, N
    Bats, JW
    Katsoulis, DE
    Suto, M
    Tecklenburg, RE
    Zank, GA
    [J]. CHEMISTRY OF MATERIALS, 2000, 12 (11) : 3402 - 3418
  • [3] Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area
    Ben, Teng
    Ren, Hao
    Ma, Shengqian
    Cao, Dapeng
    Lan, Jianhui
    Jing, Xiaofei
    Wang, Wenchuan
    Xu, Jun
    Deng, Feng
    Simmons, Jason M.
    Qiu, Shilun
    Zhu, Guangshan
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (50) : 9457 - 9460
  • [4] A priori phase prediction of zeolites: Case study of the structure-directing effects in the synthesis of MTT-type zeolites
    Burton, Allen W.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (24) : 7627 - 7637
  • [5] Hybrid Porous Materials with High Surface Area Derived from Bromophenylethenyl-Functionalized Cubic Siloxane-Based Building Units
    Chaikittisilp, Watcharop
    Sugawara, Ayae
    Shimojima, Atsushi
    Okubo, Tatsuya
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (20) : 6006 - 6014
  • [6] Issues in the synthesis of crystalline molecular sieves: Towards the crystallization of low framework-density structures
    Corma, A
    Davis, ME
    [J]. CHEMPHYSCHEM, 2004, 5 (03) : 304 - 313
  • [7] ZEOLITE AND MOLECULAR-SIEVE SYNTHESIS
    DAVIS, ME
    LOBO, RF
    [J]. CHEMISTRY OF MATERIALS, 1992, 4 (04) : 756 - 768
  • [8] Ordered porous materials for emerging applications
    Davis, ME
    [J]. NATURE, 2002, 417 (6891) : 813 - 821
  • [9] Taxonomy of periodic nets and the design of materials
    Delgado-Friedrichs, Olaf
    O'Keeffe, Michael
    Yaghi, Omar M.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (09) : 1035 - 1043
  • [10] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks
    Eddaoudi, M
    Moler, DB
    Li, HL
    Chen, BL
    Reineke, TM
    O'Keeffe, M
    Yaghi, OM
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) : 319 - 330