Effect of base additives on the selective hydrogenolysis of glycerol over Ru/TiO2 catalyst

被引：82

作者：

Feng, Jian ^{[1
]}

Wang, Jinbo ^{[1
]}

Zhou, Yafen ^{[1
]}

Fu, Haiyan ^{[1
]}

Chen, Hua ^{[1
]}

Li, Xianjun ^{[1
]}

机构：

[1] Sichuan Univ, Dept Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Peoples R China

来源：

CHEMISTRY LETTERS | 2007年 / 36卷 / 10期

关键词：

D O I：

10.1246/cl.2007.1274

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Under mild reaction conditions (170 degrees C, 3 MPa), glycerol is hydrogenolyzed to 1,2-propanediol with very high selectivity at high conversion using Ru/TiO2 as catalyst in basic aqueous solution. The base aids the initial dehydrogenation of glycerol to glyceraldehyde and promotes the dehydration of glyceraldehyde to 2-hydroxyacrolein.

引用

收藏

页码：1274 / 1275

页数：2

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