Intercalation in Layered Metal-Organic Frameworks: Reversible Inclusion of an Extended π-System

被引：120

作者：

Arslan, Hasan K. ^{[1
]}

Shekhah, Osama ^{[1
]}

Wieland, D. C. Florian ^{[2
]}

Paulus, Michael ^{[2
]}

Sternemann, Christian ^{[2
]}

Schroer, Martin A. ^{[2
]}

Tiemeyer, Sebastian ^{[2
]}

Tolan, Metin ^{[2
]}

Fischer, Roland A. ^{[3
]}

Woell, Christof ^{[1
]}

机构：

[1] Karlsruhe Inst Technol, IFG, D-76344 Eggenstein Leopoldshafen, Germany

[2] Tech Univ Dortmund, Fak Phys, DELTA, D-44221 Dortmund, Germany

[3] Ruhr Univ Bochum, Bochum, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 21期

关键词：

DESIGN; GROWTH; SOLIDS;

D O I：

10.1021/ja2037996

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the synthesis of layered [Zn-2 (bdc)(2)(H2O)(2)] and [Cu-2(bdc)(2)(H2O)(2)] (bdc = benzdicarboxylate) metal organic frameworks (MOF) carried out using the liquid-phase epitaxy approach employing self-assembled monolayer (SAM) modified Au-substrates. We obtain Cu and Zn MOF-2 structures, which have not yet been obtained using conventional, solvothermal synthesis methods. The 2D Cu2+ dimer paddle wheel planes characteristic for the MOF are found to be strictly planar, with the planes oriented perpendicular to the substrate. Intercalation of an organic dye, DXP, leads to a reversible tilting of the planes, demonstrating the huge potential of these surface-anchored MOFs for the intercalation of large, planar molecules.

引用

页码：8158 / 8161

页数：4

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