Nickel-mediated selective carbonylation routes to thiocarbamates

被引：31

作者：

Jacob, J

Reynolds, KA

Jones, WD ^{[1
]}

Godleski, SA

Valente, RR

机构：

[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

[2] Eastman Kodak Co, Rochester, NY 14650 USA

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 05期

关键词：

D O I：

10.1021/om000947+

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The nickel complexes Ni(PPh3)(2)X-2 (X = CI Br) have been found to be active for the selective oxidative coupling of aryl thiols with secondary amines and carbon monoxide to give thiocarbamates. With added oxygen, the reaction is catalytic, although competitive oxidation. of the thiol is problematic.

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页码：1028 / 1031

页数：4

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