Simple rhodium-chlorophosphine pre-catalysts for the ortho-arylation of phenols

被引：73

作者：

Bedford, Robin B. ^{[1
]}

Betham, Michael ^{[1
]}

Caffyn, Andrew J. M. ^{[2
]}

Charmant, Jonathan P. H. ^{[1
]}

Lewis-Alleyne, Lesley C. ^{[1
,2
]}

Long, Philip D. ^{[1
]}

Polo-Ceron, Dorian ^{[1
,3
]}

Prashar, Sanjiv ^{[3
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[2] Univ W Indies, Dept Chem, St Augustine, Trinidad Tobago

[3] Univ Rey Juan Carlos, Dept Quim Inorgan & Analit, Madrid 28993, Spain

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 08期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b718128k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Simple chlorodiisopropylphosphine adducts of rhodium, either pre-formed or formed in situ, prove to be highly effective catalysts for the ortho-arylation of phenols.

引用

页码：990 / 992

页数：3

共 13 条

[1] Catalytic intermolecular ortho-arylation of phenols [J].

Bedford, RB ;

Limmert, ME .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (22) :8669-8682

[2] The catalytic intermolecular orthoarylation of phenols [J].

Bedford, RB ;

Coles, SJ ;

Hursthouse, MB ;

Limmert, ME .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (01) :112-114

[3] Transition metal catalyzed oxidative functionalization of carbon-hydrogen bonds [J].

Dick, AR ;

Sanford, MS .

TETRAHEDRON, 2006, 62 (11) :2439-2463

[4] C-C bond formation via double C-H functionalization: Aerobic oxidative coupling as a method for synthesizing heterocoupled biaryls [J].

Dwight, Timothy A. ;

Rue, Nicholas R. ;

Charyk, Dagmara ;

Josselyn, Ryan ;

DeBoef, Brenton .

ORGANIC LETTERS, 2007, 9 (16) :3137-3139

[5]

Dyker G, 2005, HANDBOOK OF C-H TRANSFORMATIONS: APPLICATIONS IN ORGANIC SYNTHESIS, VOL 1, pV

[6] Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation [J].

García-Cuadrado, D ;

Braga, AAC ;

Maseras, F ;

Echavarren, AM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (04) :1066-1067

[7] Proton-abstraction mechanism in the palladium-catalyzed intramolecular arylation:: Substituent effects [J].

Garcia-Cuadrado, Domingo ;

de Mendoza, Paula ;

Braga, Ataualpa A. C. ;

Maseras, Feliu ;

Echavarren, Antonio M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (21) :6880-6886

[8] Synthesis of new chiral monodentate phosphite ligands and their use in catalytic asymmetric hydrogenation [J].

Hua, ZH ;

Vassar, VC ;

Ojima, I .

ORGANIC LETTERS, 2003, 5 (21) :3831-3834

[9] Catalytic and highly regioselective cross-coupling of aromatic C-H substrates [J].

Hull, Karni L. ;

Sanford, Melanie S. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (39) :11904-+

[10] SYNTHESES AND X-RAY CRYSTAL-STRUCTURES OF HIGHLY DISSOCIATED RHODIUM(I) PHOSPHINE COMPLEXES USING VERY BULKY PHOSPHINE-LIGANDS [J].

MURRAY, BD ;

HOPE, H ;

HVOSLEF, J ;

POWER, PP .

ORGANOMETALLICS, 1984, 3 (05) :657-663

← 1 2 →