Hard hydrogenated carbon films with low stress

被引:100
作者
Lacerda, RG [1 ]
Marques, FC [1 ]
机构
[1] Univ Estadual Campinas, Inst Fis Gleb Wataghin, BR-13083970 Campinas, SP, Brazil
关键词
D O I
10.1063/1.121874
中图分类号
O59 [应用物理学];
学科分类号
摘要
Analysis of hard a-C:H films with low stress prepared by methane plasma decomposition is reported. Films with hardness as high as 14 GPa and stress as low as 0.5 GPa were obtained. These films have a high Raman I-d/I-g ratio (similar to 1.0), and small Tauc's band gap (similar to 0.4 eV). This letter also supplies strong evidence that the subimplantation deposition model, used to explain the formation of la-C and ta-C:H films, is also valid for a-C:H films deposited by methane plasma decomposition. It is proposed that the rigidity of the films is basically provided by a matrix of dispersed cross-linked sp(2) sites, in addition to the contribution of the sp(3) sites. (C) 1998 American Institute of Physics.
引用
收藏
页码:617 / 619
页数:3
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