Organometallic Approaches to Carbon-Sulfur Bond Formation

被引：147

作者：

Bichler, Paul ^{[1
]}

Love, Jennifer A. ^{[1
]}

机构：

[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada

来源：

C-X BOND FORMATION | 2010年 / 31卷

关键词：

Carbon-sulfur; Cross-coupling; Catalysis; Bond activation; CROSS-COUPLING REACTIONS; PALLADIUM-CATALYZED SYNTHESIS; UNSYMMETRICAL DIARYL SULFONES; FORMING REDUCTIVE ELIMINATION; ARYL BORONIC ACIDS; TRANSITION-METAL; C-S; TERMINAL ALKYNES; VINYL SULFIDES; STEREOSELECTIVE-SYNTHESIS;

D O I：

10.1007/978-3-642-12073-2_3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The transition metal mediated synthesis of carbon-sulfur (C-S) bonds is possible with a variety of simple and tailored metal complexes. This chapter serves to illustrate developments over the last decade involving the catalytic synthesis of C-S bonds with various transition metals, focusing on cross-coupling reactions and addition to pi-bonds.

引用

页码：39 / 64

页数：26

共 261 条

[21] Alkyl- and arylthiolation of aryl halides catalyzed by fluorinated bis-imino-nickel NNN pincer complexes [NiCl2{C5H3N-2,6-(CHNArf)2}] [J].

Baldovino-Pantaleón, O ;

Hernández-Ortega, S ;

Morales-Morales, D .

ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (1-2) :236-242

[22] Unsymmetrical diaryl Sulfones through palladium-catalyzed coupling of aryl boronic acids and arylsulfonyl chlorides [J].

Bandgar, BP ;

Bettigeri, SV ;

Phopase, J .

ORGANIC LETTERS, 2004, 6 (13) :2105-2108

[23] CARBON-HETEROATOM BOND-FORMING REDUCTIVE ELIMINATION - MECHANISM, IMPORTANCE OF TRAPPING REAGENTS, AND UNUSUAL ELECTRONIC EFFECTS DURING FORMATION OF ARYL SULFIDES [J].

BARANANO, D ;

HARTWIG, JF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (10) :2937-2938

[24] An efficient copper catalyst for the formation of sulfones from sulfinic acid salts and aryl iodides [J].

Baskin, JM ;

Wang, ZY .

ORGANIC LETTERS, 2002, 4 (25) :4423-4425

[25] Copper-catalyzed synthesis of vinyl sulfides [J].

Bates, CG ;

Saejueng, P ;

Doherty, MQ ;

Venkataraman, D .

ORGANIC LETTERS, 2004, 6 (26) :5005-5008

[26] A mild and efficient new synthesis of aryl sulfones from boronic acids and sulfinic acid salts [J].

Beaulieu, C ;

Guay, D ;

Wang, ZY ;

Evans, DA .

TETRAHEDRON LETTERS, 2004, 45 (16) :3233-3236

[27] Element-element addition to alkynes catalyzed by the group 10 metals [J].

Beletskaya, I ;

Moberg, C .

CHEMICAL REVIEWS, 1999, 99 (12) :3435-3461

[28] Element-element additions to unsaturated carbon-carbon bonds catalyzed by transition metal complexes [J].

Beletskaya, Irina ;

Moberg, Christina .

CHEMICAL REVIEWS, 2006, 106 (06) :2320-2354

[29] Addition reactions of E-E and E-H bonds to triple bond of alkynes catalyzed by Pd, Pt, and Ni complexes (E=S, Se) [J].

Beletskaya, Irina P. ;

Ananikov, Valentine P. .

PURE AND APPLIED CHEMISTRY, 2007, 79 (06) :1041-1056

[30] Unusual influence of the structures of transition metal complexes on catalytic C-S and C-Se bond formation under homogeneous and heterogeneous conditions [J].

Beletskaya, Irina P. ;

Ananikov, Valentine P. .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2007, 2007 (21) :3431-3444

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