Stereoselective construction of nitrile-substituted cyclopropanes

被引：48

作者：

Denton, Justin R. ^{[1
]}

Cheng, Kevin ^{[1
]}

Davies, Huw M. L. ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 10期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1039/b719175h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nitrile-substituted cyclopropanes are readily synthesized in a stereocontrolled fashion from the intermolecular cyclopropanation between 2-diazo-2-phenylacetonitrile and electron-rich olefins, catalyzed by the chiral dirhodium complex, Rh-2(S-PTAD)(4).

引用

收藏

页码：1238 / 1240

页数：3

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