Diastereoselective formation and optical activity of an M4L6 cage complex

被引：67

作者：

Argent, SP

Riis-Johannessen, T

Jeffery, JC

Harding, LP

Ward, MD ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[3] Univ Huddersfield, Dept Chem & Biol Sci, Huddersfield HD1 3DH, W Yorkshire, England

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 37期

关键词：

D O I：

10.1039/b509239f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chiral bridging ligand affords a single diastereoisomer of tetrahedral M4L6 cage complex in which the optical rotation of each ligand is increased by a factor of 5 on coordination.

引用

页码：4647 / 4649

页数：3

共 43 条

[11]

Dietrich-Buchecker C, 1999, CHEM-EUR J, V5, P1432, DOI 10.1002/(SICI)1521-3765(19990503)5:5<1432::AID-CHEM1432>3.0.CO

[12]

2-C

[13]

Eliel E.L., 1994, Stereochemistry of Organic Compounds

[14]

Fatin-Rouge N, 2001, HELV CHIM ACTA, V84, P1694, DOI 10.1002/1522-2675(20010613)84:6<1694::AID-HLCA1694>3.0.CO

[15]

2-T

[16] Selective molecular recognition, C-H bond activation, and catalysis in nanoscale reaction vessels [J].

Fiedler, D ;

Leung, DH ;

Bergman, RG ;

Raymond, KN .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :349-358

[17]

Fleming JS, 1998, ANGEW CHEM INT EDIT, V37, P1279, DOI 10.1002/(SICI)1521-3773(19980518)37:9<1279::AID-ANIE1279>3.0.CO

[18]

2-Q

[19] Supramolecular stereocontrol of octahedral metal-centered chirality. Ligand modulation [J].

Jodry, JJ ;

Frantz, R ;

Lacour, J .

INORGANIC CHEMISTRY, 2004, 43 (11) :3329-3331

[20]

Jodry JJ, 2000, CHEM-EUR J, V6, P4297, DOI 10.1002/1521-3765(20001201)6:23<4297::AID-CHEM4297>3.0.CO

← 1 2 3 4 5 →