Enantioselective Rh-catalyzed hydrogenation of vinyl carboxylates with monodentate phosphite ligands

被引：80

作者：

Reetz, MT ^{[1
]}

Goossen, LJ ^{[1
]}

Meiswinkel, A ^{[1
]}

Paetzold, J ^{[1
]}

Jensen, JF ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 17期

关键词：

D O I：

10.1021/ol035076p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkyl-substituted vinylcarboxylates, which normally show poor enantioselectivity in Rh-catalyzed hydrogenation with traditional chiral diphosphines, undergo highly enantioselective reactions with BINOL- and carbohydrate-based monophosphite ligands.

引用

页码：3099 / 3101

页数：3

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